石墨基体NiHCF薄膜的离子交换性能

以石墨为基体材料,采用电沉积和毛细化学沉积方法制备出电活性NiHCF薄膜.通过EDS和SEM考察了薄膜组成及其形貌,在1 mol/l KNO3溶液中采用电势循环可逆地置入与释放K离子,比较了不同制备方法得到的NiHCF薄膜的电活性、离子交换容量、再生性能和循环寿命;在1 mol/l(KNO3+CsNO3)混合溶液中测定了不同浓度下薄膜的伏安特性曲线,分析了薄膜对Cs+/K+的选择性.实验表明,石墨基体上制得的NiHCF膜能实现电化学控制的离子交换(ESIX)过程;两种方法制得的薄膜对Cs+均有较强的选择性,其中电沉积膜的再生速度高于化学沉积膜,而化学沉积膜的寿命高于电沉积膜.     

Ф100mm单槽自动轧管机组的技术改造与实践

介绍了应用先进的工艺和设备对Ф100mm单槽自动轧管机组生产线以及局部生产设备进行的技术改造。改造后的机组扩大了产品规格，增加了品种，提高丁产品质量，特别是提高了产品的几何尺寸精度，使企业获得了生机。其经验亦可作为其他Ф100mm自动轧管机组改造借鉴。     

8170缸体裂纹缺陷的探讨

对8170缸体裂纹缺陷进行了探讨分析,通过优化铸件结构,改进合金化工艺,完善浇注工艺以及随流孕育与炉前孕育工艺相结合等措施,使裂纹缺陷解决。     

Effects of NH4F on the deposition rate and buffering capability of electroless Ni-P plating solution

The deposition rate and buffering capability of alkaline electroless Ni-P plating solution containing ammonium fluoride (NH₄F) have been investigated. When the NH₄F concentration is below 10 g L^− 1, the deposition rate is improved with the addition of NH₄F, reaching the maximum value at 2 g L^− 1. The buffering capability of solutions is found to be improved with increasing NH₄F concentration. Due to the improvement of buffering capability, refined and compact Ni-P coatings with homogeneous elemental distribution of P have been achieved. Therefore, both the corrosion resistance and microhardness of Ni-P coatings are significantly improved. The mechanism of NH₄F improving the deposition rate and the buffering capability is discussed.     

离子硫氮磷共渗层表层形貌与相结构研究

采用扫描电镜、能谱仪、Ｘ射线衍射仪等分析研究了离子硫氮碳共渗层表面与次表面形貌特征与相结构，探讨了其形成机制．结果表明：硫氮碳共渗表层为以硫化物颗粒组成的多层层状结构，其成分及层数随共渗气氛硫势的变化而变化；次表层为致密的氮碳化物层和氮、碳扩散层，这种渗层结构是其具有良好减摩性、跑合性与耐磨性的原因．     

TW3M煤气发生炉的节能降耗技术改造与管理改进

针对钢管热处理加热用TW3M煤气发生炉存在的煤气量达不到设计要求、有气固相盲区、设备易损坏、煤耗和水耗高、管理脱节、管理制度不到位等问题,江苏诚德钢管股份有限公司通过实施一系列节能降耗技术改造并加强了生产管理,基本上解决了所存在的问题,使煤气产量提高了46.7%,煤气质量有了较大的提高,煤气发生炉的维修周期从3～6个月延长到2～3年,生产成本大幅度降低。     

带凸缘拉伸件可调式落料拉伸复合模设计

介绍了带凸缘拉伸件可调式落料拉伸复合模设计,实现对凸缘直径尺寸可以进行调整以实现一定公差要求的模具结构.     

凝胶注模成型研究进展

凝胶注模成型是20世纪90年代初美国橡树岭国家实验室首创的胶态成型工艺.该工艺利用有机单体聚合反应形成的三维网络凝胶特性,使陶瓷悬浮体注入模具后原位固化成陶瓷坯体.它具有坯体均匀、坯体密度高、坯体强度高、近净尺寸成型等显著优点.本文全面阐述了凝胶注膜成型的近十年来的研究进展,并对其研究前景进行了展望.     

Alternative tribological coatings to electrodeposited hard chromium: a critical review

ABSTRACT

The traditional importance of hard chromium electroplating in surface engineering is recognised and the key features of this well-established technology are summarised. Despite the high hardness, corrosion protection and wear resistance of chromium electrodeposits, a number of alternative coating compositions and application techniques have been developed for specific applications in tribology. Environmental challenges associated with hard chromium electroplating are highlighted and the need to develop and evaluate alternative coatings is stressed. Key examples of the alternative coatings are described, including their method of application, microstructure and tribological performance in controlled service environments. Research needs requiring rapid development are highlighted. A summary is given of the most competitive coatings and those having the potential to match the performance of hard chromium in selected applications are identified.     

Study of modeling and simulation of full digital controlled PMIG／MAG welding system based on Matlab／Simulink

This paper presents an integrated simulation model for full digital controlled PMIG/MAG welding system with Matlab/Simulink, and it consists of power inverter, digital control system and dynamic arc-load model. An integrated simulation study was done for fuU digital PMIG/MAG welding, and a method of connecting dynamic arc-load model to the system with controlled current source was presented, in addition, the simulation results were utilized to study the issues of digital control PMIG/MAG welding in this paper. The experimental results validated the developed simulation model, and this simulation study can be applied in implementation of the full digital PMIG/MAG welding and analysis of system dynamic process.